
1) Fiend
Found on
https://www.crosswordclues.com/clue/archvillain

1) The Joker, for Batman
Found on
https://www.crosswordclues.com/clue/archvillain

archvillain, archvillainy Chief villain, begetter, or ringleader of villainy. Cross references of word families related directly, or indirectly, to: 'master, lead, leading, ruler, ruling, govern': -agogic; agon-; -crat; dom-; gov-; magist-; poten-; regi-; tyran-.
Found on
http://www.wordinfo.info/words/index/info/view_unit/2391/2
No exact match found.