polydentate ligand. A ligand that has more than one atom that coordinates directly to the central atom in a complex. Polydentate ligands are called chelating agents when two or more coordinating atoms are attached to the same metal ion in a complex. For example, EDTA or ethylenediaminotetracetic acid is a hexadentate ligand of calcium ion. Found on http://antoine.frostburg.edu/chem/senese/101/glossary/p.shtml