
Photoelectrolysis occurs in a photoelectrochemical cell when light is used for electrolysis. In other words, photoelectrolysis is the conversion of light into a current, and then the division of a molecule using that current. Photoelectrolysis` main attractiveness to many engineers and technologists is its potential to divide water into hydrogen ....
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http://en.wikipedia.org/wiki/Photoelectrolysis

photoelectrolysis, photoelectrolytic a process that uses light energy rather than electrical energy to produce a chemical change in an electrolytic solution.
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http://www.wordinfo.info/words/index/info/view_unit/2803/8

Photoelectrolysis occurs in a photoelectrochemical cell when light is used for electrolysis. In other words, photoelectrolysis is the conversion of light into an electric current that will drive an otherwise non-spontaneous chemical reaction. Photoelectrolysis can potentially of divide water to hydrogen and oxygen (water splitting).
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https://www.icore-solarfuels.org/
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