1) Manganese mineral 
Groutite is a manganese oxide mineral with formula Mn3+O(OH). It is a member of the diaspore group and is trimorphous with manganite and feitknechtite. It forms lustrous black crystals in the orthorhombic system. It occurs in weathered banded iron formations, metamorphosed manganese ore bodies and hydrothermal ore environments. It was first descri...