Autoacceleration (Gel Effect, Trommsdorff-Norrish Effect) is a dangerous reaction behavior that can occur in free radical polymerization systems. It is due to the localized increases in viscosity of the polymerizing system that slow termination reactions. The removal of reaction obstacles therefore causes a rapid increase in the overall rate of re...
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(from the article `industrial polymers, chemistry of`) ...reactions, but on a large industrial scale it can be dangerous, since heat causes an increase in the reaction rate, and faster reactions in turn ...
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