1) Case-hardened 2) Converted to solid form 3) Emotionally hardened 4) Fully set 5) Got set 6) Got tough 7) Hard 8) Hard-boiled 9) Like dried cement or plaster 10) Like some criminals 11) Made callous 12) Made tougher 13) Protected against attack 14) Used of persons Found on https://www.crosswordclues.com/clue/hardened
Hard'ened (-'nd) adjective Made hard, or harder, or compact; made unfeeling or callous; made obstinate or obdurate; confirmed in error or vice. Syn. -- Impenetrable; hard; obdurate; callous; unfeeling; unsusceptible; insensible. See Obdurate . Found on http://www.encyclo.co.uk/webster/H/13