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Cross-conjugation
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Cross-conjugation
Cross-conjugation is a special type of conjugation in a molecule, when in a set of three Pi bonds only two pi-bonds interact with each other by conjugation, the third one is excluded from interaction. In classical terms it means that the strict alternation of single and double bonds—CH=CH–CH=CH... Found op http://en.wikipedia.org/wiki/Cross-conjugation
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cross-conjugation
In a system XC6H4GY this is conjugation involving the substituent X, the benzene ring, and the side-chain connective-plus-reaction site GY, i.e. either X is a +R group and GY is a -R group, or X is a -R group and GY is a +R group. In Hammett correlations this situation can lead... Found op http://www.chem.qmul.ac.uk/iupac/gtpoc/CoCy.html
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